Common Multilayer Plastic Materials for Food Packaging & Their Properties

Core Structure of Multilayer Films

Typically 3-7 layers with specific functions:

Layer PositionPrimary FunctionCommon Materials
Outer LayerProtection, printability, durabilityPET, PP, PA (Nylon), Paper
Barrier LayerBlock oxygen, moisture, aromasEVOH, PVDC, Aluminium foil, Metallized film, PA
Tie/Adhesive LayerBond incompatible layersSpecialized tie resins (like maleic anhydride grafted PE/PP)
Seal LayerHeat sealing, food contactLDPE, LLDPE, mLLDPE, ionomers (Surlyn®), EVA

Common Multilayer Structures & Applications

StructureTypical CompositionKey PropertiesCommon Applications
PET//PEPET / Adhesive / PEGood moisture barrier, printable, stiffDried foods, nuts, cookies
OPP//PEBiaxially Oriented PP / PEGood moisture barrier, clear, cost-effectiveCrackers, snack bars
PET/EVOH/PEPET / Tie / EVOH / Tie / PEHigh oxygen barrier, moisture protectionTomato sauce, juices, deli meats
PA/PENylon / PEPuncture resistant, good oxygen barrierVacuum-packed meats, cheese, fish
PET/Met/PEPET / Metallized layer / PEExcellent light & oxygen barrier, flexiblePotato chips, coffee, chocolate
Paper/PE/Alu/PEPaper / PE / Aluminum foil / PETotal barrier, stiff, opaqueAseptic liquid packaging (juice boxes)
PP/EVOH/PPPP / Tie / EVOH / Tie / PPRetortable, high barrier, microwave-safeReady meals, pet food, soups

Performance Advantages vs. Monolayer Films

PropertyMultilayer Improvement
Shelf Life2-10x extension through tailored barriers
StrengthCombine puncture resistance with sealability
CostOptimize material use (expensive barrier only where needed)
FunctionalityIncorporate peelable seals, easy-open features
Print QualitySuperior graphics on outer layers